Experimental observation of high thermal conductivity in boron arsenide

First-principles determination of ultrahigh thermal conductivity of boron arsenide: a competitor for diamond?

We have calculated the thermal conductivities (κ) of cubic III-V boron compounds using a predictive first principles approach. Boron arsenide is found to have a remarkable room temperature κ over 2000 W m(-1) K(-1); this is comparable to those in diamond and graphite, which are the highest bulk values known. We trace this behavior in boron arsenide to an interplay of certain basic vibrational p...

Thermal conductivity behavior of boron carbides.

Knowledge of the thermal conductivity of boron carbide is necessary o evaluate its potential for high temperature thermoelectric energy conversion applications. We have measured the thermal diffusivity of hot -pressed boron carbide B1_xCx samples as a function of composition (0.1 < x < 0.2), temperature (300 K to 1700 K) and temperature cycling. These data in concert with density and specific h...

Experimental observation of boron nitride chains.

We report the formation and characterization of boron nitride atomic chains. The chains were made from hexagonal boron nitride sheets using the electron beam inside a transmission electron microscope. We find that the stability and lifetime of the chains are significantly improved when they are supported by another boron nitride layer. With the help of first-principles calculations, we prove th...

Superior thermal conductivity in suspended bilayer hexagonal boron nitride

We reported the basal-plane thermal conductivity in exfoliated bilayer hexagonal boron nitride h-BN that was measured using suspended prepatterned microstructures. The h-BN sample suitable for thermal measurements was fabricated by dry-transfer method, whose sample quality, due to less polymer residues on surfaces, is believed to be superior to that of PMMA-mediated samples. The measured room t...

High Quality Substrates for Boron Arsenide Semiconductor Devices